摘要: 通过田间植株直接施药-定期采样提取-高效液相色谱分析的方法,研究了多菌灵在杭白菊胎菊、菊花及土壤中的残留消解动态,测定了多菌灵在杭白菊胎菊和菊花中的最终残留量,并在室内探讨了不同温度对干胎菊和干菊花中多菌灵消解的影响。结果表明:在0.675和1.00 kg/hm2 2个施药剂量下,多菌灵在杭白菊土壤、胎菊和菊花中的消解半衰期分别为7.98~8.34 d、3.90~4.05 d和3.31~3.45 d;不同温度下,干胎菊和干菊花中多菌灵的半衰期存在显著性差异(P2的剂量喷雾施用2次,第2次施药后21 d时多菌灵在干胎菊和干菊花中的残留量分别为0.182~0.294 mg/kg和0.371~0.381 mg/kg,远低于我国制定的多菌灵在怀菊中的最大残留限量标准(5 mg/kg)。
关键词: 多菌灵 / 胎菊 / 菊花 / 消解动态 / 最终残留Abstract: Spraying carbendazim 50% WP in Chrysanthemum morifolium and soil,the residue decline dynamics were investigated in field at two different concentrations,the final residue in bud and flower were determined,and the impact of different temperature on carbendazim declined in dry bud and flower was researched.The results showed that when carbendazim were sprayed at the concentration of 0.675 and 1.00 kg/hm2,respectively,the half-life was 7.98-8.34 days in soil,3.90-4.05 days in bud and 3.31-3.45 days in flower.At different temperatures,there were significant differences between dry bud and flower in half-life (P2 carbendazim was sprayed twice a year,the residues of carbendazim in dry bud and flower were 0.182-0.294 mg/kg and 0.371-0.381 mg/kg respectively 21 days after spraying second times,which is below the MRL of the Huai fios chrysanthemum (5 mg/kg).
[1]WANG Huikang,XIA Yi,YANG Zhengyu,et al.Recent advances in the discovery and development of flavonoids and their analogues as antitumor and anti-HIV agent[J].Adv Exp Med Biol,1998,439:191-225.
[2]HU Changqi,CHEN Ke,SHI Qian,et al.Anti-AIDS agents,10.Acacetin-7-O-β-D-galactopyranoside,an anti-HIV principle from chrysanthemum morifolium and a structure-activity correlation with some related flavonoids[J].J Nat Prod,1994,57(1):42-51.
[3] 刘乾开,朱国念.新编农药使用手册[M].2版.上海:上海科学技术出版社,1999:309. LIU Qiankai,ZHU Guonian.Pesticide Manual[M].2nd Ed.Shanghai:Shanghai Science and Technology Press,1999:309.(in Chinese) [4]VAN GESTEL C A M,KIOOLHAAS J E,SCHALLNA β H J,et al.Ring-testing and field-validation of a terrestrial model ecosystem (TME)—an instrument for testing potentially harmful substances:effects of carbendazim on nutrient cycling[J].Ecotoxicology,2004,13(1-2):119-128.
[5]SARRIF A M,ARCE G T,KRAHN D F,et al.Evaluation of carbendazim for gene mutations in the salmonella/ames plate-incorporation assay:The role of aminophenazine impurities[J].Mutat Res,1994,321(1-2):43-56.
[6]BHATTACHERJEE A K,PANDEY B K,PRAKASH O.Persistence and dissipation of carbendazim residues in mango fruits after pre-and post-harvest applications[J].J Food Sci Tech,2009,46(4):347-349.
[7]MOHAPATRA S,AWASTHI M D,AHUJA A K,et al.Persistence and dissipation of carbendazim residue in/on grape berries[J].Pest Res J,1998,10(1):95-97.
[8] 樊丹,甘小泽,卢耀英,等.多菌灵在茶叶中的残留动态研究[J].农业环境科学学报,2005,24(增):298-300. FAN Dan,GAN Xiaoze,LU Yaoying,et al.Dissipation dynamics of carbendazim in tea[J].J Agro-environ Sci,2005,24(S1):298-300.(in Chinese) [9] 游子涵,陈智东,柳训才,等.油菜植株及其土壤中多菌灵残留检测及动态[J].农药,2006,45(8):552-553. YOU Zihan,CHEN Zhidong,LIU Xuncai,et al.Carbendazim residue detection and dissipation dynamics in rapeseed plants and soil[J].Agrochemicals,2006,45(8):552-553.(in Chinese) [10] 刘双双,杨仁斌,陈海平,等.多菌灵在水稻及土壤中的消解动态和残留规律研究[J].农业环境科学学报,2011,31(2):357-361. LIU Shuangshuang,YANG Renbin,CHEN Haiping,et al.Residue and degradation of carbendazim in rice and soil[J].J Agro-environ Sci,2011,31(2):357-361.(in Chinese) [11] 郑志琴,魏朝军,张志勇,等.多菌灵在草莓与土壤中的残留动态研究[J].农业环境科学学报,2010,29(10):1948-1952. ZNENG Zhiqin,WEI Chaojun,ZHANG Zhiyong,et al.Residue dynamics of carbendazim in strawberry and soil[J].J Agro-Environ Sci,2010,29(10):1948-1952.(in Chinese) [12] 金仁耀,桂文君,寿林飞,等.多菌灵在柑橘和土壤中的残留及降解动态研究[J].江苏农业科学,2005(2):111-114. JIN Renyao,GUI Wenjun,SHOU Linfei,et al.Residues and degradation dynamics of carbendazim in orange and soil[J].Jiangsu Agric Sci,2005(2):111-114.(in Chinese) [13] 田金改,金红宇,彭方,等.多菌灵在人参生长期的残留动态研究[J].中草药,2006,37(9):1413-1415. TIAN Jingai,JIN Hongyu,PENG Fang,et al.Residue of carbendazim at growth period of ginseng[J].Chin Tradit Herbal Drugs,2006,37(9):1413-1415.(in Chinese) [14] 魏厚道,林建,王天玉,等.多菌灵在浙麦冬及其土壤中的消解动态研究[J].农药学学报,2009,11(4):467-471. WEI Houdao,LIN Jian,WANG Tianyu,et al.Residue decline dynamics of carbendazim in Radix ophiopogonis and soil[J].Chin J Pestic Sci,2009,11(4):467-471.(in Chinese) [15] 吴加伦,王怀昌,杨娜娜,等.高效液相色谱法测定元参、黄芩和杭白菊中的多菌灵残留[J].农药学学报,2010,12(4):489-493. WU Jialun,WANG Huaichang,YANG Nana,et al.Determination of carbendazim residue in Radix scrophulariae,Radix scutellariae and Flos chrysanthemi by high performance liquid chromatography[J].Chin J Pestic Sci,2010,12(4):489-493.(in Chinese) [16] NY/T 788—2004.农药残留试验准则[S].北京:中国农业出版社,2004. NY/T 788—2004.Guide-lines for pesticide residue testing[S].Beijing:China Agriculture Press,2004.(in Chinese) [17] 王中,侯宪文,邓晓,等.多菌灵在香草兰和土壤中的残留动态[J].生态环境学报,2009,18(2):535-539. WANG Zhong,HOU Xianwen,DENG Xiao,et al.Study on residue dynamics of carbendazim in Vanilla planifolia Andrew and soil[J].Ecol Environ Sci,2009,18(2):535-539.(in Chinese) [18] GB/T 20353—2006.地理标志产品:怀菊花[S].北京:中国标准出版社,2006:12. GB/T 20353—2006.Product of geographical indication:Huai fios chrysanthemum[S].Beijing:China Standards Press,2006:12.(in Chinese)相关知识
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