伍晚花

花匠小妙招
2024-11-24 05:50

研究兴趣为超分子光化学和三线态湮灭上转换发光。近年来，针对TTA上转换的多步能量下行过程造成的反斯托克斯位移小以及固相上转换效率低的难题，合成了系列新型三重态光敏剂与湮灭剂为组装基元，创建了多层级组装体新结构，实现了光敏剂激发态能量损失的高效降低及传递效率的大幅提高，获得1.08 eV TTA-UC发光反斯托克斯位移的最高纪录，将固相TTA-UC发光效率提高至目文献报道的最大值23.8%。建立了单分子手性反转的精准调控新方法，通过创新组装策略实现了手性光学活性的数量级放大，构筑了多种智能化分子机器和具有高发光不对称因子(glum)的圆偏振发光(CPL)材料。

至今已发表SCI论文126篇，总引用7000余次，H-index为46；作为（共同）通讯作者/一作在Acc. Chem. Res. (1), J. Am. Chem. Soc. (5), Angew. Chem. Int. Ed. (2), Nat. Commun. (1), Nat. Protoc. (1) 等高水平期刊发表论文60余篇，其中影响因子大于10的论文13篇。先后入选国家优青、四川省学带、四川大学校百人b计划等；荣获《Chin. Chem. Lett.》学术新星奖和《Sci. China Chem.》新锐科学家称号。目前担任《Front. Chem.》副主编,《Chin. Chem. Lett.》编委，中国感光学会青年理事和《Curr. Opin. Green Sust.》（IF: 9.3, JCR Q1期刊）客座编辑。授权中国发明专利4项，实用新型专利1项。

国家自然科学基金委“优秀青年基金”（国家优青，2024年获批）

国家自然科学基金委面上项目，基于超分子自组装的敏化室温磷光与TTA上转换荧光的可控调节，2021年获批

国家自然科学基金委面上项目，超分子组装提高TTA上转换效率的研究， 2019年获批

国家自然科学基金委青年项目，分子作用诱导的高效三重态湮灭光子上转换体系的研究，2014年获批

四川省科技厅国际科技合作计划，超分子自组装提高固相TTA上转换发光的研究，2021年获批

四川省科技厅自由探索项目，超分子功能化三线态湮灭剂的合成与应用，2019年获批

四川大学青年科技学术带头人培育项目，2020年

四川大学创新火花项目，2018年

中国博士后基金特别资助，2018年

四川省博士后科研项目特别资助（一等），2019年

中国博士后基金面上，2017年

大连理工大学精细化工国家重点实验室开放课题，2015年

四川大学青年教师科研启动基金，2014年

《Front. Chem.》副主编

《Chin. Chem. Lett.》编委

《Curr. Opin. Green Sust.》客座编辑

2023年，《Chin. Chem. Lett.》学术新星奖

He, C.; Huang, R.; Wei, L.; He, Q; Liu, J.; Chen, J.; Gao, G.; Yang, C.; Wu, W.* Uncovering the mask of sensitizers to switch on the TTA-UC emission by supramolecular host-guest complexation. Chin. Chem. Lett., 2024, 110103

Mao, Y.; Ma, J.; Ji, J.; Wang, Y.; Wu, W.*; Yang, C.* Crown aldoxime ethers: Their synthesis, structure, acid-catalyzed/photo-induced isomerization and adjustable guest binding, Chin. Chem. Lett., 2024, 35, 109927

Fan, C.; Wei, X.; Wu, W.*; Yang, C.*, Expanding the Anti-Stokes Shift of TTA-UC to 1.04 eV by Chemical Tuning of BODIPY-Based Organic Photosensitizers. Org Lett 2024, 26, 950-954.

He, Q.; Wei, L.; He, C.; Yang, C.*; Wu, W.*, Supramolecular Annihilator with DPA Parallelly Arranged by Multiple Hydrogen-Bonding Interactions for Enhanced Triplet–Triplet Annihilation Upconversion, Molecules 2024, 29, 2203

Ji, J.; Wei, X.; Wu, W.*; Yang, C.*, Asymmetric Photoreactions in Supramolecular Assemblies. Acc. Chem. Res. 2023, 56, 1896-1907.

Wei, L.; Gao, F.; He, C.; He, Q.; Jin, P.; Rong, Y.; Zhao, T.; Yang, C.; Wu, W.*, A New Sensitization Strategy for Achieving Organic RTP in Aqueous Solution: Tunable RTP and UC Emission in Supramolecular TTA-UC Systems. Sci. China. Chem. 2023, 66, 3546-3554

Zhu, S.; Wei, L.; Sun, Y.; Yang, C.; Wu, W.*, NIR/Visible Light Double Beam Synergistically Enhanced the Emission of Triplet‐Triplet Annihilation Upconversion via Thermal Lensing Effect. Adv. Opt. Mater. 2023, 11, 2300484.

Sun, Y.; Wei, L.; Zhu, S.; Jin, P.; He, C.; He, Q.; Yang, C.; Wu, W.*, Stimuli-responsive triplet-triplet annihilation upconversion with guanidyl functionalized annihilators for enhanced ratiometric sensing of trace water in MeOH. Sens. Actuators 2023, 387, 133764.

Jin, P.; Liang, W.; Rong, Y.; Wu, W.*; Gou, M.; Tang, Y.; Yang, C.*, Remarkable iodine uptake by aniline-based macrocyclic arenes through a reverse dissolution mechanism. J. Mater. Chem. A 2023, 11, 11126-11132.

Zhao, T.; Wu, W.*; Yang, C.*, Chiroptical regulation of macrocyclic arenes with flipping-induced inversion of planar chirality. Chem. Commun. 2023, 59, 11469-11483.

Wei, L.; Yang, C.*; Wu, W.*, Recent advances of triplet–triplet annihilation upconversion in solvent-free solid materials. Mater. Chem. Front. 2023, 7, 3194-3208.

Wei, L.; Yang, C.; Wu, W.*, Recent Advances of Stereolithographic 3D Printing Enabled by Photon Upconversion Technology. Curr. Opin. Green Sust. 2023, 100851.

Gao, F.; Yu, X.; Liu, L.; Chen, J.; Lv, Y.; Zhao, T.; Ji, J.; Yao, J.*; Wu, W.*; Yang, C.*, Chiroptical switching of molecular universal joint triggered by complexation/release of a cation: A stepwise synergistic complexation. Chin. Chem. Lett. 2023, 34, 107558.

Wei, L.; Fan, C.; Rao, M.; Gao, F.; He, C.; Sun, Y.; Zhu, S.; He, Q.; Yang, C.; Wu, W.*, Triplet-Triplet Annihilation Upconversion in Laponite/PVP Nanocomposites: Absolute Quantum Yields up to 23.8% at Solid-State and Application to Anti-counterfeiting. Materials Horizons, 2022, 9, 3048-3056.

Wei, X.; Ji, J.; Nie, Y.; Tang, L.; Rao, M.; Wang, X.; Wu, W.*; Su, D.; Zhong, Z.; Yang, C.*, Synthesis of cyclodextrin derivatives for enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate. Nat. Protoc. 2022, 17, 2494-2516.

Ji, J.; Wei, X.; Wu, W.*; Fan, C.; Zhou, D.; Kanagaraj, K.; Cheng, G.; Luo, K.; Meng, X. G.; Yang, C.*, The More the Slower: Self-Inhibition in Supramolecular Chirality Induction, Memory, Erasure, and Reversion. J. Am. Chem. Soc. 2022, 144, 1455-1463.

Zhang, D.; Liang, W.; Yi, J.; Chen, J.; Lv, Y.; Zhao, T.; Xiao, C.; Xie, X.; Wu, W*.; Yang, C*., Photochemical graft of γ-cyclodextrin’s interior leading to in-situ charge-transfer complexes with unusual regioselectivity and its application in 3D photo-printing. Sci. China Chem. 2022, 65, 1149-1156.

Yu, X.; Gao, F.; Zhao, W.; Lai, H.; Wei, L.; Yang, C.; Wu, W.*, BODIPY-conjugated bis-terpyridine Ru(II) complexes showing ultra-long luminescence lifetimes and applications to triplet-triplet annihilation upconversion. Dalton Trans. 2022, 51, 9314-9322.

Tu, C.; Wu, W.*; Liang, W.; Zhang, D.; Xu, W.; Wan, S.; Lu, W.; Yang, C.*, Host–Guest Complexation-Induced Aggregation Based on Pyrene-Modified Cyclodextrins for Improved Electronic Circular Dichroism and Circularly Polarized Luminescence. Angew. Chem. Int. Ed. 2022, e202203541.

Rao, M.; Fan, C.; Ji, J.; Liang, W.; Wei, L.; Zhang, D.; Yan, Z.; Wu, W.*; Yang, C.*, Catalytic Chiral Photochemistry Sensitized by Chiral Hosts-Grafted Upconverted Nanoparticles. ACS Appl Mater Interfaces 2022, 14, 21453-21460.

Yu, X.; Wan, S.; Wu, W.*; Yang, C.*; Lu, W., gamma-Cyclodextrin-based [2]rotaxane stoppered with gold(I)-ethynyl complexation: phosphorescent sensing for nitroaromatics. Chem. Commun. 2022, 58, 6284-6287.

Yao, J.; Wu, W.*; Xiao, C.; Su, D.; Zhong, Z.; Mori, T.; Yang, C*., Overtemperature-protection intelligent molecular chiroptical photoswitches. Nat. Commun. 2021, 12 (1), 2600.

Yu, X.; Wu, W.*; Zhou, D.; Su, D.; Zhong, Z.; Yang, C., Bisindole [3]arenes—Indolyl Macrocyclic Arenes Having Significant Iodine Capture Capacity. CCS Chem. 2021, 1945-1953.

Tian H.; Yu X.; Yao J.; Gao G.; Wu W.*; Yang C.*. Supramolecular spectral/visual detection of urinary polyamines through synergetic/competitive complexation with gamma-CD and CB[7] Chem. Commun. 2021, 57, 1806-1809.

Mi, Y.; Ma J.; Liang W.; Xiao C.; Wu W.*; Zhou D.; Yao J.; Sun W.; Sun J.*; Gao G.; Chen X.; Chruma J. J.; Yang C.* Guest-Binding-Induced Interhetero Hosts Charge Transfer Crystallization: Selective Coloration of Commonly Used Organic Solvents. J. Am. Chem. Soc. 2021, 143, 1553-1561.

Liu, C.; Yao, J.; Xiao, C.; Zhao, T.; Selvapalam, N.; Zhou, C.; Wu, W.*; Yang, C.*, Electrochemiluminescent Chiral Discrimination with a Pillar[5]arene Molecular Universal Joint-Coordinated Ruthenium Complex. Org Lett 2021, 23 (10), 3885-3890.

Hao Taotao; Yang Yongsheng; Liang Wenting; Fan Chunying; Wang Xin; Wu Wanhua*; Chen Xiaochuan; Fu Haiyan*; Chen Hua; Yang Cheng*, Trace mild acid-catalysed Z → E isomerization of norbornene-fused stilbene derivatives: intelligent chiral molecular photoswitches with controllable self-recovery. Chem. Sci. 2021, 12, 2614-2622.

Guo Qian; Li Guojuan; Rao Ming; Wei Lingling; Gao Fanrui; Wu Wanhua*; Yang Qingshan*; Cheng Guo*; Yang Cheng*. A dendritic DPA annihilator—syntheses, photophysical properties and application for co-assembling enhanced triplet-triplet annihilation upconversion. Dyes and Pigments 2020, 182, 108643

Kanagaraj Kuppusamy; Liang Wenting; Rao Ming; Yao Jiabin; Wu Wanhua*; Cheng Guo; Ji Jiecheng; Wei Xueqing; Peng Chao; Yang Cheng*. pH-Controlled Chirality Inversion in Enantiodifferentiating Photocyclodimerization of 2-Antharacenecarboxylic Acid Mediated by gamma-Cyclodextrin Derivatives.. Org Lett 2020, 22 (14), 5273-5278.

Ji Jiecheng; Wu Wanhua*; Wei Xueqing; Rao Ming; Zhou Dayang; Cheng Guo; Gong Qiyong; Luo Kui*; Yang Cheng*. Synergetic effects in the enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by beta-cyclodextrin-pillar[5]arene-hybridized hosts. Chem. Commun. 2020, 56, 6197-6200.

Peng Chao; Liang Wenting; Ji Jiecheng; Fan Chunying; Kanagaraj Kuppusamy; Wu Wanhua*; Cheng Guo; Su Dan; Zhong Zhihui; Yang Cheng*. Pyrene-tiaraed pillar[5]arene: Strong intramolecular excimer emission applicable for photo-writing. Chin. Chem. Lett. 2021, 32, 345-348.

Kanagaraj Kuppusamy; Xiao Chao; Rao Ming; Fan Chunying; Borovkov Victor*; Cheng Guo; Zhou Dayang; Zhong Zhihui; Su Dan; Yu Xingke; Yao Jiabin; Hao Taotao; Wu Wanhua*; Chruma J. Jason; Yang Cheng*. A Quinoline-Appended Cyclodextrin Derivative as a Highly Selective Receptor and Colorimetric Probe for Nucleotides. iScience 2020, 23, 100927.

Mi Yan; Yao Jiabin; Ma Jingyu; Dai Ling; Xiao Chao; Wu Wanhua*; Yang Cheng*, Fulleropillar[4]arene: The Synthesis and Complexation Properties. Org Lett 2020, 22, 2118-2123. （封面论文）

Ji Jiecheng; Li Yizhou; Xiao Chao; Cheng Guo; Luo Kui; Gong Qiyong; Zhou Dayang; Chruma J. Jason; Wu Wanhua*; Yang Cheng*, Supramolecular enantiomeric and structural differentiation of amino acid derivatives with achiral pillar[5]arene homologs. Chem. Commun. 2020, 56, 161-164

Chunying Fan, Lingling Wei, Tong Niu, Ming Rao, Guo Cheng, Jason J. Chruma, Wanhua Wu*, and Cheng Yang*. Efficient Triplet-Triplet Annihilation Upconversion with an Anti-Stokes Shift of 1.08 eV Achieved by Chemically Tuning Sensitizers. J. Am. Chem. Soc. 2019, 141, 15070−15077.

Chunying Fan, Jiabin Yao, Guojuan Li, ChengGuo, WanhuaWu*, Dan Su, Zhihui Zhong, Dayang Zhou, Yuliang Wang, Jason J. Chruma, and Cheng Yang*. Precise Manipulation of Temperature‐Driven Chirality Switching of Molecular Universal Joints through Solvent Mixing. Chem. Eur. J. 2019, 25, 12526-12537. DOI: 10.1002/chem.201902676

Ming Rao, Wanhua Wu*, Cheng Yang*. Effects of Temperature and Host Concentration on the Supramolecular Enantiodifferentiating [4 + 4] Photodimerization of 2-Anthracenecarboxylate through Triplet-Triplet Annihilation Catalyzed by Pt-Modified Cyclodextrins. Molecules, 2019, 24, 1502.

Chao Xiao, Wenting Liang, Wanhua Wu*, Kuppusamy Kanagaraj, Yafen Yang, Ke Wen, Cheng Yang*. Resolution and Racemization of a Planar-Chiral A1/A2-Disub-stituted Pillar[5]arene. Symmetry, 2019, 11, 773.

Guojuan Li, Chunying Fan, Guo Cheng, Wanhua Wu* and Cheng Yang*. Synthesis, enantioseparation and photophysical properties of planar-chiral pillar [5] arene derivatives bearing fluorophore fragments. Beilstein J. Org. Chem. 2019, 15, 1601-1611.

Hongxia Lai, Ting Zhao, Yurong Deng, Chunyin Fan, Wanhua Wu*, Cheng Yang*. Assembly-enhanced triplet-triplet annihilation upconversion in the aggregation formed by Schiff-base Pt (II) complex grafting-permethyl-β-CD and 9, 10-diphenylanthracence dimer. Chin. Chem. Lett. 2019, 30, 1979-1983.

Jiecheng Ji, Syama S. Chereddy, Yi Ren, Xingming Chen, Dan Su, Zhihui Zhong, Tadashi Mori, Yoshihisa Inoue*, Wanhua Wu* and Cheng Yang*, A BODIPY- based near infrared fluorescent probe for Fe3+ in water. J. Photochem. Photobiol. A 2018, 355, 78. DOI.org/10.1016/j.jphotochem.2017.10.043

Xueqin Wei#, Wanhua Wu#, Ryohei Matsushita#, Zhiqiang Yan#, Dayang Zhou, Jason J. Chruma, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue*, and Cheng Yang*. Supramolecular Photochirogenesis Driven by Higher-Order Complexation: Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate to Slipped Cyclodimers via a 2: 2 Complex with β-Cyclodextrin. J. Am. Chem. Soc., 2018, 140, 3959. DOI: 10.1021/jacs.7b12085

范春英; 伍晚花*; 杨成*, 聚集体中的三重态-三重态湮灭上转换.有机化学, 2018, 38, 1377. DOI: 10.6023/cjoc201712034.

Ling Dai#, Wanhua Wu#, Wenting Liang, Wentong Chen, Xingke Yu, Jiecheng Ji, Chao Xiao and Cheng Yang. Enhanced Chiral Recognition by γ-Cyclodextrin-Cucurbit [6] uril-Cowheeled [4] Pseudorotaxanes. Chem. Commun. 2018, 54, 2643-2646. DOI: 10.1039/c8cc00840j

Jigao Yi, Wenting Liang, Xueqin Wei, Jiabin Yao, Zhiqiang Yan, Dan Sua, Zhihui Zhong, Guowei Gao, Wanhua Wu*, Cheng Yang*. Switched enantioselectivity by solvent components and temperature in photocyclodimerization of 2-anthracenecarboxylate with 6A,6X-diguanidio−γ-cyclodextrins. Chin. Chem. Lett., 2018, 29, 87-90. DOI: 10.1016/j.cclet.2017.05.004

Ming Rao, Kuppusamy Kanagaraj, Chunying Fan, Jiecheng Ji, Chao Xiao, Xueqin Wei, Wanhua Wu* and Cheng Yang*. Photocatalytic Supramolecular Enantiodifferentiating Dimerization of 2Anthracenecarboxylic Acid through Triplet−Triplet Annihilation. Org. Lett. 2018, 20, 1680−1683. DOI: 10.1021/ acs.orglett.8b00520

Wei Xu, Wenting Liang, Wanhua Wu*, Chunying Fan, Ming Rao, Dan Su, Zhihui Zhong, Cheng Yang*. Supramolecular Assembly‐Improved Triplet–Triplet Annihilation Upconversion in Aqueous Solution. Chem. Eur. J., 2018, 24, 16677. DOI: 10.1002/chem.201804001

Jianlin Wu, Wenting Liang, Tong Niu, Wanhua Wu*, Dahui Zhou, Chunying Fan, Jiecheng Ji, Guowei Gao*, Jian Meng, Cheng Yang*. Induced chirality sensing through formation and aggregation of the chiral imines double winged with pyrenes or perylenes. Chem. Commun. 2018, 54, 9206. DOI:10.1039/C8CC03660H

Jiabin Yao#, Wanhua Wu#, Wenting Liang, Yujun Feng, Dayang Zhou, Jason J. Chruma, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue, Cheng Yang* Temperature-Driven Planar Chirality Switching of a Pillar[5]arene-Based Molecular Universal Joint. Angew. Chem., Int. Ed. 2017, 56 (24), 6869-6873.

Chunying Fan#, Wanhua Wu#, Jason J. Chruma, Jianzhang Zhao, Cheng Yang*, Enhanced Triplet-Triplet Energy Transfer and Upconversion Fluorescence through Host-Guest Complexation. J. Am. Chem. Soc. 2016, 138, 15405-15412.

Chao Xiao, Weiye Zhao, Dayang Zhou, Yan Huang, Ye Tao, Wanhua Wu*, Cheng Yang*. Recent advance of photochromic diarylethenes-containing supramolecular systems., Chin. Chem. Lett. 2015, 26, 817-824.

Wanhua Wu, Jianzhang Zhao*, Jifu Sun, Ling Huang, Xiuyu Yi, Red-light excitable fluorescent platinum(ii) bis(aryleneethynylene) bis(trialkylphosphine) complexes showing long-lived triplet excited states as triplet photosensitizers for triplet-triplet annihilation upconversion. J. Mater. Chem. C 2013, 1 (4), 705-716.

Wanhua Wu, Jifu Sun, Xiaoneng Cui, Jianzhang Zhao*, Observation of the room temperature phosphorescence of Bodipy in visible light-harvesting Ru(ii) polyimine complexes and application as triplet photosensitizers for triplet-triplet-annihilation upconversion and photocatalytic oxidation. J. Mater. Chem. C 2013, 1 (30), 4577-4589.

Wanhua Wu, Lianlian Liu, Xiaoneng Cui, Caishun Zhang, Jianzhang Zhao*. Red-light-absorbing diimine Pt(II) bisacetylide complexes showing near-IR phosphorescence and long-lived 3IL excited state of Bodipy for application in triplet-triplet annihilation upconversion. Dalton Trans. 2013, 42 (40), 14374-14379.

Wanhua Wu, Xiaoneng Cui, Jianzhang Zhao*, Hetero Bodipy-dimers as heavy atom-free triplet photosensitizers showing a long-lived triplet excited state for triplet-triplet annihilation upconversion. Chem. Commun. 2013, 49 (79), 9009-9011.

Wanhua Wu, Jianzhang Zhao*, Jifu Sun, Song Guo. Light-Harvesting Fullerene Dyads as Organic Triplet Photosensitizers for Triplet-Triplet Annihilation Upconversions. J. Org. Chem. 2012, 77 (12), 5305-5312.

Wanhua Wu, Jianzhang Zhao*, Huimin Guo, Jifu Sun, Shaomin Ji, Zilong Wang, Long-lived room-temperature near-IR phosphorescence of BODIPY in a visible-light-harvesting N(caret)C(caret)N PtII-acetylide complex with a directly metalated BODIPY chromophore. Chem. - Eur. J. 2012, 18 (7), 1961-1968.

Wanhua Wu, Shaomin Ji, Wenting Wu, Jinyin Shao, Huimin Guo, Tony D. James, Jianzhang Zhao* Ruthenium(II)-Polyimine-Coumarin Light Harvesting Molecular Arrays: Design Rationale and Application for Triplet-Triplet-Annihilation-Based Upconversion., Chem. - Eur. J. 2012, 18 (16), 4953-4964.

Wanhua Wu, Song Guo, Jianzhang Zhao* Development of triplet-triplet annihilation upconversion. Zhongguo Kexue: Huaxue 2012, 42 (10), 1381-1398.

Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Jianzhang Zhao*. Tuning the emission property of carbazole-caped cyclometalated platinum(II) complexes and its application for enhanced luminescent oxygen sensing. J. Organomet. Chem. 2011, 696 (11-12), 2388-2398.

Wanhua Wu, Jifu Sun, Wenting Wu, Jianzhang Zhao*, Huimin Guo. Tuning the emissive triplet excited states of platinum(II) Schiff base complexes with pyrene, and application for luminescent oxygen sensing and triplet-triplet-annihilation based upconversions. Dalton Trans. 2011, 40 (43), 11550-11561.

Wanhua Wu, Huimin Guo, Wenting Wu, Shaomin Ji, Jianzhang Zhao*. Organic Triplet Sensitizer Library Derived from a Single Chromophore (BODIPY) with Long-Lived Triplet Excited State for Triplet-Triplet Annihilation Based Upconversion. J. Org. Chem. 2011, 76 (17), 7056-7064.

Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Lina Chi, Jinyin Shao, Jianzhang Zhao*. Tuning the emission properties of cyclometalated platinum(II) complexes by intramolecular electron-sink/arylethynylated ligands and its application for enhanced luminescent oxygen sensing. J. Mater. Chem. 2010, 20 (43), 9775-9786.

Wanhua Wu, Shaomin Ji, Wenting Wu, Huimin Guo, Xin Wang, Jianzhang Zhao*, Zhonggang Wang, Enhanced luminescence oxygen sensing property of Ru(II) bispyridine complexes by ligand modification. Sens. Actuators, B 2010, 149 (2), 395-406.