摘要: 采用顶空固相微萃取气相色谱质谱联用技术和离子色谱技术分析"中国苦水玫瑰"花瓣香气构成,探讨玫瑰香气构成与栽培土壤构成的相关性。样品花瓣中初步定性59种香气成分,OAV≥1的香气成分中香茅醇、香叶醇、苯甲醛、香茅醛为实验样品共有,α-蒎烯在上新沟和大同样品中OAV≥1;橙花醇在大同和红城样品中OAV≥1、辛酸乙酯仅在大同样品中OAV≥1;乙酸香茅酯仅在红城样品中OAV≥1。定量分析了栽培土壤的9种构成组分,其中上新沟样品的Mg2+、全氮和速效钾含量最高;大同样品的Ca2+含量最高;红城样品的Na+、Cl-、SO2-、HCO3+和有效磷含量显著高于(p<0.05)上新沟和大同样品。相关性分析显示样品香气总释放量与栽培土壤的Cl-、HCO3+和有效磷呈正相关,与速效钾呈负相关;香气成分香茅醇和香叶醇与Mg2+、全氮和速效钾呈正相关,橙花醇和香茅醛与其呈负相关,Mg+与香茅醛的相关性显著;辛酸乙酯与Ca2+呈正相关,而香茅醇和苯甲醛与其呈负相关;香茅醇和苯甲醛与SO42-和有效磷呈正相关,辛酸乙酯与其呈负相关;苯甲醛与Na+和Cl-呈正相关性,α-蒎烯与其呈负相关。
Abstract: The aroma components of‘Chinese Kushui rose petal'were analysed by headspace solid phase micro extraction and gas chromatography mass spectrometry( HS- SPME- GC / MS),and cultivated soil samples were analysed by Ion chromatography,and the correlation was discussed about aroma compounds in the petal and components of cultivated soil. The results showed that 59 compounds were primarily identified in sample petals.Citronellol,geraniol,benzaldehyde,citronellal were common components( OAV≥1) in the samples,α- pinene was components( OAV ≥ 1) in Shangxingou and Datong samples,nerol was components( OAV ≥ 1) in Datong and Hongchen samples,octanoic acid ethyl ester was components( OAV≥1) in Datong samples,and citronella acetate was components( OAV ≥ 1) in Hongchen samples. 9 components of cultivated soil were quantified,Mg2+,total nitrogen and available potassium content were the highest in Shangxingou samples,Ca2+ content was the highest in Datong samples,Na+,Cl-,SO42-,HCO3- and phosphorus cont ent were significantly( p < 0.05) higher in Hongchen samples than they were in Shangxingou and Datong samples. Correlation analysis showed that the amount of total rose aroma had positive correlation with content of Cl-,HCO3- and phosphorus of cultivated soil,and amount of total rose aroma had negative correlation with content of available potassium.Citronellol and geraniol had positive correlation with content of Mg2+,total nitrogen and available potassium,while geraniol and citronellol had negative correlation with content of Mg2+,total nitrogen and available potassium,and the correlation of Mg+and Citronellal was significantly.Octanoic acid ethyl ester had positive correlation with content of Ca2+,but geraniol and benzaldehyde had negative correlation with content of Ca2+. Geraniol and benzaldehyde had positive correlation with content of SO42- and phosphorus,while octanoic acid ethyl ester had negative correlation withcontent of SO42-and phosphorus. Benzaldehyde had positive correlation with content of Na+and Cl-,whileα- pinene had negative correlation with content of Na+ and Cl-.
[1] 薛郭渊,陈宁,李兆林.苦水玫瑰鲜花香气成分研究[J].植物学报,1989,31(4):289-295. [2] 袁颂东,岳春,邹沛.玫瑰型香精调香研究[J].食品工业科技,2002,33(22):172-177. [3]Bhaskaruni Rajeswara Rao,Arun Bhattachary.Yield and Chemical Composition of Rose-Scented Geranium(Pealrgonium Species)Oil at Different Times of Harvesting[J].Journal of Essential Oil Research,2014,9:18-57.
[4] 周围,周小平,赵国宏,等.2002.中国苦水玫瑰油香气成分的研究[J].色谱,2002,20(6):560. [5] 江云兵,熊兴泉.乙酸香茅酯的绿色合成与结构表征[J].华侨大学学报:自然科学版,2014,35(1):47-51. [6] 刘先章,王振洪,蒋同夫.合成香叶醇和橙花醇的研究[J].林产化学与工业,1989,4(4):11-18. [7] 杨海宽.芳樟醇合成橙花叔醇的工艺研究[D].长沙:中南林业科技大学,2010. [8] 刘玲,余义勋.植物香气的合成代谢的分子生物学研究进展[J].中国生物工程杂志,2008,28(6s):289-294. [9]Rakesh Kumar,Saurabh Sharma,Swati Sood,et al.Agnihotri,Agronomic interventions for the improvement of essential oil content and composition of damask rose(Rosa damascena Mill.)under western Himalayas[J].Industrial Crops and Products,2013,48:171-177.
[10]Bakkali F,Averbeck S,Averbeck D Idaomar M,et al.Biological Effects of Essential Oil-A review[J].Food and Chemical Toxicology,2008,46:446-457.
[11]Patrick J,Dunphy.Location and biosynthesis of monoterpenyl fatty acyl esters in rose petals[J].Phytochemistry,2006,47:1110-1119.
[12] 董迹芬,边金霖,朱全武,等.茶叶香气与产地土壤条件的关系[J].浙江大学学报:农业与生命科学版,2012,39(3):309-317. [13] 也协峰,刘国顺,凌爱芬,等.烤烟巨豆三烯酮含量与土壤理化性状的典型相关分析[J].生态学报,2009,29(8):4423-4430. [14] 黄锦霞,肖迪,段美洋,等.不同锌肥施用量对香稻产量和糙米香气含量的影响[J].华北农学报,2008,23(增刊):290-292. [15] 徐雪芹,许葛飞,王维刚.微量元素对烤烟香气品质的影响[J].广东农业科学,2012,12(3):30-34. [16] 王建凌,方欣,杨长青,等.植物萜类次生代谢及其调控[J].中国科学,2013,43(12):1030-1046. [17]B Hethelyi,S Szarka,Lemberkovics,et al.SPME-GC/MS Identification of Aroma Compounds In Rose Flowers[J].Acta Agronomica Hungarica,2010,58(3):283-287.
[18] 陈劼,谢建春.国产玫瑰精油的化学成分及香气特征[J].中国食品添加剂,2007,7(16):66-69. [19] 陈红艳,廖蓉苏,杨今朝.玫瑰花挥发性化学成分的分析研究[J].食品科技,2011,36(11):186-189. [20] 杨荣华.白柠檬果皮油特征香气成分的评价[J].食品发酵与工业,2012,26(3):31-34. [21]Ramasamy Ravi,Maya Prakash,K Keshava Bhat.Aroma characterization of coriander(Coriandrum sativum L.)oil samples[J]Eur Food Res Technol,2007,225:367-374.
[22] 韦旭阳,陶永胜.通过气味活性成分评价干红葡萄酒的香气质量[J].中国食品学报,2012,12(10):188-195. [23] 于倩,蒋玉梅.李霁昕,等.苦水玫瑰及其混合发酵酒的香气比较分析[J].食品工业科技,2012,33(22):172-177. [24] 肖庆礼,黄帅,刘国顺,等.施磷对低磷土壤烤烟化学成分和香气物质含量的影响更[J].河南农业大学学报,2009,43(5):491-496. [25] 李静,夏建国.氮磷钾与茶叶品质关系的研究综述[J].中国农学通报,2005,21(1):62-65. [26] 林郑和.茶树对缺磷的生理生化反应与适应[D].福州:福建农林大学,2009. [27]Bohlmann J,Meyer-Gauen G,Croteau R.Plant terpenoid synthases:molecular biology and phylogenetic analysis[J].Proc Natl Acad Sci USA,1998,95:4126-4133.
[28]Christianson D W.Structural biology and chemistry of the terpenoid cyclases[J].Chem Rev,2006,106:3412-3442.
[29]Green S,Squire C J,Nieuwenhuizen N J,et al.Defining the potassium binding region in an apple terpene synthase[J].J Biol Chem,2009,284:8661-8669.
[30]Hyatt D C,Croteau R.Mutational analysis of a monoterpene synthase reaction:altered catalysis through directed mutagenesis of(-)-pinene synthase from Abies grandis[J].Arch Biochem Biophys,2005,439:222-233.
[31] 吴宇,高蕾,曹民杰,等.2007.植物硫营养代谢调控与生物学功能[J].植物学通报,24(6):735-761. [32]Ola Lasekan,Ng Siew See.Key volatile aroma compounds of three black velvet tamarind(Dialium)fruit species[J]Food Chemistry,2015,168:561-565.
[33] 李娟.植物钾钙镁素营养的研究进展[J].福建稻麦科技,2007,25(1):39-42. [34] 边金霖,董迹芬,林杰,等.钾肥食用对茶鲜叶香气组分的影响[J].福建农林大学学报:自然科学版,2007,41(6):601-607.相关知识
苦水玫瑰精油及花渣中色素的提取纯化
苦水玫瑰的SWOT分析
苦水玫瑰花香四溢
玫瑰精油和玫瑰花水的制备及其护肤功效介绍.pdf
苦水玫瑰和普通玫瑰的区别 苦水玫瑰功效与作用
2017年中国玫瑰花市场前景研究报告
晚潮|沙漠里的苦水玫瑰
中国玫瑰之乡在哪里?全中国产玫瑰花最好的10个地方盘点
环境因素对盛花期茉莉鲜花香气的影响
玫瑰花精油产品行业产业链分析
网址: 栽培土壤对“中国苦水玫瑰花”香气构成的影响 https://m.huajiangbk.com/newsview513084.html
上一篇: 秋季园林绿化苗木养护有哪些注意事 |
下一篇: 上年纪的人常在花间走更健康 |